Ethyl 2-(1H-1,2,3-benzotriazol-1-yl)acetate
نویسندگان
چکیده
The title compound, C(10)H(11)N(3)O(2), was synthesized by the reaction of 1H-benzotriazole with ethyl 2-chloro-acetate in ethanol. The non-H atoms, excluding the benzotriazol-1-yl group, are almost coplanar (r.m.s. deviation of the non-H atoms = 0.0409 Å). The dihedral angle formed between this plane and the benzotriazole ring is 79.12 (5)° In the crystal, weak inter-molecular C-H⋯N and C-H⋯O inter-actions help to consolidate the three-dimensional network.
منابع مشابه
Chemistry of Peptide Materials
Aib α-Aminoisobutyric acid or Cα-methylalanine (αMe)Phe Cα-methylphenylalanine (αMe)Val Cα-methylvaline BOP (Benzotriazol-1-yloxy)tris(dimethylamino)phosphonium CIP 2-Chloro-1,3-dimethylimidazolidium phosphate Db z g Cα,α-dibenzylglycine Deg Cα,α-diethylglycine Dφg Cα,α-diphenylglycine Dp n g Cα,α-di-n-propylglycine EDC 1-(3-Dimethylamino)propyl-3-ethylcarbodiimide HATU 2-(1H-7-aza-1,2,3-benzot...
متن کامل2-(1H-Benzotriazol-1-yl)acetohydrazide
The title compound, C(8)H(9)N(5)O, was synthesized by the reaction of ethyl 2-(benzotriazol-1-yl)acetate with hydrazine hydrate in ethanol. In the amide group, the C-N bond is relatively short [1.3283 (16) Å], suggesting some degree of electronic delocalization in the mol-ecule. In the crystal structure, mol-ecules are linked into infinite chains along the a axis by inter-molecular O-H⋯N hydrog...
متن کاملTetraaqua{1-[(1H-1,2,3-benzotriazol-1-yl)methyl]-1H-1,2,4-triazole}sulfatocobalt(II) dihydrate
In the title complex, [Co(SO(4))(C(9)H(8)N(6))(H(2)O)(4)]·2H(2)O, the Co(II) ion is six-coordinated by one N atom from a 1H-1,2,3-benzotriazol-1-yl)meth-yl]-1H-1,2,4-triazole ligand, one O atom from a monodentate sulfate ligand and four water mol-ecules in a slightly distorted octa-hedral geometry. The sulfate ligand is rotationally disordered over two sets of sites with refined occupancies of ...
متن کاملTetraaqua{1-[(1H-1,2,3-benzotriazol-1-yl)methyl]-1H-imidazole}sulfatomanganese(II) dihydrate
In the title complex, [Mn(SO(4))(C(10)H(9)N(5))(H(2)O)(4)]·2H(2)O, the Mn(2+) cation is six-coordinated by one N atom from a 1-[(1H-1,2,3-benzotriazol-1-yl)meth-yl]-1H-imidazole ligand and five O atoms from one monodentate sulfate ligand and four water mol-ecules in a distorted octa-hedral geometry. In the crystal, adjacent mol-ecules are linked through O-H⋯O and O-H⋯N hydrogen bonds into a thr...
متن کاملTetraaqua{1-[(1H-1,2,3-benzotriazol-1-yl)methyl]-1H-1,2,4-triazole}sulfatocadmium dihydrate
In the title complex, [Cd(SO(4))(C(9)H(8)N(6))(H(2)O)(4)]·2H(2)O, the Cd(II) ion is six-coordinated by one N atom from a 1-[(1H-1,2,3-benzotriazol-1-yl)meth-yl]-1H-1,2,4-triazole ligand and by five O atoms from four water mol-ecules and one monodentate sulfate anion in a distorted octa-hedral geometry. The sulfate tetra-hedron is rotationally disordered over two positions in a 0.651 (12):0.349 ...
متن کامل